Decomposition of Hydroperoxides with Bis (<I>O</I>, <I>O</I>-diisobutylthiophosphoryl) disufide
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概要
- 論文の詳細を見る
Decomposition of cumyl hydroperoxide and <I>t</I>-butyl hydroperoxide with bis (<I>O</I>, <I>O</I>-diisobutylthiophosphoryl) disulfide (the isobutyl disulfide) consisted of a radical decomposition at the initial stage and an ionic decomposition at the later stage. After the complete decomposition of <I>t</I>-butyl hydroperoxide with the isobutyl disulfide, the reaction solution was separated into several components, and some of components derived from the isobutyl disulfide was identified and used for decomposition of <I>t</I>-butyl hydroperoxide as catalyst. It was found that sulfuric acid was most effective for the ionic decomposition. The formation mechanism of sulfuric acid was also proposed.
- 社団法人 日本油化学会の論文
著者
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OSA Tetsuo
Department of Biotechnology, Faculty of Bioscience and Bioengineering, Tokyo Institute of Technology
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Ohkatsu Yasukazu
Department Of Applied Chemistry Faculty Of Engineering Kogakuin Univ.
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UEDA Hidemaru
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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KIKKAWA Kazumi
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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OHKATSU Yasukazu
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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OSA Tetsuo
Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo
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Kikkawa Kazumi
Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo
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