The Photo-induced Addition of Acetic Acid to Olefins

スポンサーリンク

概要

• 論文の詳細を見る

• The photo-induced addition of acetic acid to ethylene gave butyric acid. Small amounts of hexanoic, octanoic, 2-ethylbutyric, and 2-ethylhexanoic acids, and neutral substances were also formed. The presence of a small amount of di-tert. butyl peroxide was effective to form butyric acid. Main neutral substances were dibutyl and di (2-ethylhexyl) phthalates. <BR>A straight-chain saturated fatty acid was also obtained in an excellent conversion of a 1-olefin by the photo-induced addition of acetic acid to the 1-olefin [acetic acid : 1-olefin, 200 : 1 (mol)]. It was assumed that a ketone and an ester (s) were present in the by-products.

• 日本油化学会の論文

著者

• SUHARA Yasuo

  National Chemical Laboratory for Industry

関連論文

• The Peroxide-induced Addition of Acetic Acid to Ethylene by Continuous Feeding of Ethylene and a Peroxide
• The Photo-induced Addition of Acetic Acid to Olefins
• The synthesis of 1,3-dithiolan-2-ones on the reaction of oxiranes with carbon disulfide under high pressure.
• The reaction of oxiranes with carbon disulfide under high pressure.
• The synthesis of 1,3-dithiolane-2-thione derivatives.

スポンサーリンク