フルフリルアルコールを出発原料とするシクロペンテノン類の合成

概要

論文の詳細を見る
Intramolecular rearrangement of furfuryl alcohols and the following isomerization gives cyclopentenolones. These reactions were successfully applied to the syntheses of industrially valuable cyclopentenolones : allethrolone, propargyl cyclopentenolone (alcohol moiety of pyrethroids), jasmones, and intermediates of prostaglandins. Furthermore, optically active cyclopentenolones were obtained by enzyme-catalyzed enantioselective hydrolysis.
社団法人有機合成化学協会の論文