高分子化学における有機合成の役割 (新しい高分子合成特集号)
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概要
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Several topics are discussed looking at the macromolecular synthesis from a view point of organic synthesis. Group Transfer Polymerization (GTP) which seems to be the most familiar to organic chemists is, together with another topic-ring opening metathesis polymerization (ROMP), tractable procedure capable to control the molecular weight and its distribution. Both methods provide simple and convenient ways by improving the initiation and/or the reaction conditions. Sol-gel reaction of metal alkoxides is a new field in inorganic polymer synthesis which makes the design of ceramics in molecular unit feasible and is expecting the positive participation of organic chemists. Further, the importance and valuability of the structural device and clearance are discussed for two examples-molecular recognition and polyaniline formation.
- 社団法人 有機合成化学協会の論文