酸化還元に伴う金属-炭素σ結合の開裂と生成
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概要
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Recent studies on cleavage and formation of metal-carbon σ bonds associated with redox reactions have been reviewed. The redox states of organometallic compounds as well as the steric factors of alkyl groups are shown to play essential roles to control the stabilities of metal-carbon bonds. Irreversible electron transfer processes accompanied by cleavage and formation of metal-carbon bonds are sought to be emphasized as key reaction steps in understanding the versatile reactivities of organometallic compounds from a single, unified view.
- 社団法人 有機合成化学協会の論文