有機窒素化合物の酸化, 還元による活性窒素種の発生と合成反応への応用

概要

論文の詳細を見る
Studies on reactive intermediates are important to clarify reaction mechanisms and also to design useful synthetic reactions. From this viewpoint, the generation of reactive nitrogen species and their synthetic application were studied using chemical and electrochemical oxidation and reduction. This article is organized under the following headings. 1. Introduction 2. Generation of Reactive Nitrogen Species by N-Halogenation Followed by Dehalogenation and Their Synthetic Application 2.1. Rearrangement of N-Alkylhaloamidines 2.2. Synthesis of 1, 2, 4-Oxadiazoles 2.3. Synthesis of N-Imidoylsulfilimines 2. 4. Synthesis of Δ4-1, 2, 4-Thiadiazolines 3. Generation of Nitrenes by Electrochemical Reduction of N, N-Dihalo Compounds 4. Electrochemical Generation of Reactive Nitrogen Species and Their Synthetic Application 4.1. Ammoniumyl and Aminyl Radicals 4.2. Nitrenes 4.3. Aminonitrenes 4.4. Nitrenium Ions 4.5. Reactive Aminyl Anions 4.6. Others 5. Concluding Remarks
社団法人有機合成化学協会の論文