鉄-硫黄タンパクモデルの合成と性質
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概要
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This article offers a brief description of the structures and an exposition of selected reactions of non - heme iron-sulfur protein sites and their synthetic analogs [Fe (SR) <SUB>4</SUB>] <SUP>1-, 2-</SUP>, [Fe<SUB>2</SUB>S<SUB>2</SUB> (SR) <SUB>4</SUB>] <SUP>2-, 3-</SUP>, and [Fe<SUB>4</SUB>S<SUB>4</SUB> (SR) <SUB>4</SUB>] <SUP>2-, 3-</SUP>. The properties of synthetic Fe -S complexes reveal them to be close representations of the redox centers of iron-sulfur proteins, and the analogs are useful as detailed structural models and as electron carries in some biomimetic reactions. Presented are also current observations pertinent to stabilizing the redox centers using 36-membered and cyclophane-type macrocyclic ligands as conducted in the authors laboratory.
- 社団法人 有機合成化学協会の論文