核酸光化学の新展開 : 生物化学に役に立つ新反応の開発

概要

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The authors results on the organic photochemistry of nucleic acid derivatives have been reviewed. These include, i) a novel photoreaction between thymidine and primary amines, ii) its use in determining T residues of DNA fragments in DNA sequencing, iii) new photochemical methods for C-C bond formation at C- 5 and C- 6 positions of pyrimidine nucleosides, and iv) a selective deoxygenation method of ribonucleosides to 2- deoxy-and 2, 3-dideoxyribonucleosides by utilizing photosensitized electoron-transfer reaction.
社団法人有機合成化学協会の論文