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概要
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The efficient introduction of nitrogen atom or azido group to organic molecules is important in amino derivatives or heterocycle synthesis. Most of attentions on silyl azides have been hitherto focused on their properties and heterocycle synthesis. In this article, trimethylsilyl azide (TMSA) is widely shown as a synthetic reagent, including azide formation. Trimethylsilymethyl azide (TMSMA), which is regarded as a silylated derivative of methyl azide, is also shown as such a new reagent. The advantage of using these azides in organic synthesis is presented.
- 社団法人 有機合成化学協会の論文