アセトニトリルの熱分解(その2) : 塩素存在下,アセトニトリルの熱分解
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概要
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A mixture of acetonitrile and chlorine in a molar ratio of 1/0.021.21 was heat-treated at 500800°C in a silica tube in the presence of diluent nitrogen.<BR>The liquid products were analyzed by gas chromatography, mass spectroscopy, and infrared spectroscopy to identify malononitrile, fumaronitrile, maleonitrile, βchloropropionitrile, <I>cis</I>-and <I>trans</I>-monochlorodicyanoethylenes, <I>cis</I>-and <I>trans</I>-dichlorodicyanoethylenes, and monochloroacetonitrile.
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