炭素-炭素結合活性化による選択的分子変換

概要

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Carbon-carbon bond activation of unstrained molecules using metal compounds were reviewed. Novel transformations by carbon-carbon bond activation (i) - (iii) were proposed as targets. (i) Regioselective substituent transfer. (ii) Replacement of a carbon in the skeleton by other atoms. (iii) Stereoselective recombination of a substituent. Two transformations, (i) methyl group transfer from α-position to β-position and (ii) the replacement of a carbon by an oxygen atom, were shown using zircona and/or hafnacyclopentane derivatives in this article.
社団法人有機合成化学協会の論文