メチルナフトニトリル類の重クロム酸ナトリウム水溶液酸化によるナフタリンポリカルボン酸の合成
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概要
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It is reported that both methyl and cyano groups in the following methylnaphtonitriles were converted to carboxyl groups in aqueous sodium bichromate at 255275°C for 56 hr under autogeneous pressure, although the cyano group is converted rather to an amido group by alkaline hydrolysis ; 1-cyano-2-methyl-, 4-cyano-1- methyl, 1-cyano-2, 3-dimethyl-, 1-cyano-2, 4-dimethyl-, 1-cyano-2, 6-dimethyl-, 4-cyano-1, 6-dimethyl-, 4-cyano-1, 7-dimethyl-, 1, 4-dicyano-2, 3-dimethyl-, and 1, 5- dicyano-2, 6-dimethylnaphthalene.
- 社団法人 有機合成化学協会の論文