有機リチウム化合物を用いる分子内閉環反応
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概要
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Any reaction that results in ring formation can be of considerable potential use in organic synthesis. Nucleophilic center introduced through various kinds of lithiation undergoes intramolecular bond-forming reaction with the internal electrophilic center. Furthermore, the lithiated intermediate generated in this reaction reacts with various electrophiles to afford the products which have the substituents originated from electrophiles. This paper reviews the intramolecular cyclization reaction initiated through organolithium compounds.
- 社団法人 有機合成化学協会の論文