ヘテロヘリセンの化学

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概要

• 論文の詳細を見る

• Heterohelicenes refer to ortho-condensed aromatic compounds in which heteroaromatic and benzene rings are angularly annulated such as to give helically shaped molecules. Since the first heterohelicene, dithia [6] heterohelicene, was synthesized by means of oxidative photocyclization of diarylethylene in 1968, its homologues up to [11] heterohelicene have been already reported. These molecules are asymmetric chromophores themselves and manifest the interesting structural, spectral and optical behaviors.<BR>This paper describes the studies of heterohelicenes on their preparations, reactions, structures, optical resolutions, racemizations and spectroscopies (NMR, UV, ORD, CD and MS).

• 社団法人 有機合成化学協会の論文

著者

• 山田 紘一

  城西大学薬学部

• 川面 博司

  城西大学薬学部

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• ヘテロヘリセンの化学

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