アジリジニウムイリドの分解によるエキソアルキリデンの合成(Azyl法)
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概要
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The synthesis of exoalkylidenes were accomplished via the formation of aziridinium ylid from carbonyl derivatives. The name “Azyl” reaction was proposed. Azyl reaction gave exoalkylidene derivatives in better yield with simpler process than the use of triphenylphosphine alkylidenes. The hindered or highly enolizable ketones were also converted easily to exomethylene derivatives.
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