クロロビス (η-シクロペンタジエニル) ヒドリドジルコニウム (IV) : ヒドロジルコニウム化試剤
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概要
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Hydrozirconation using chlorobis (η-cyclopentadienyl) hydridozirconium (IV) (1) has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1, 3-dienes <I>via</I> organozirconium (IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. <I>Via</I> transmetalation the zirconium intermediates also serve as, precursors of reactive organometallic complexes of metallic elements whose chemistry is well established with regard to C-C bond formation processes. Synthetic and mechanistic aspects of organozirconium chemistry are discussed.
- 社団法人 有機合成化学協会の論文