フリーデル・クラフツ・アシル化反応中間体
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In relation to Friedel-Crafts acylation, complexes of (ArH·MX<SUB>3</SUB>), (ArH·HX·MX<SUB>3</SUB>), and (RCOX·MX<SUB>3</SUB>) were chronologically reviewed on their structual formulations up to date. Properties of their complexes and their roles in the reaction were explained in terms of their differences between π-and σ-type structure. The X-ray crystal analytical results were quoted to make clear the structual small changes between π-axial and π-edgewize complexes and between ionic and nonionic complexes of (RCOX·MX<SUB>3</SUB>), and also to demonstrate the characteristics of σ-complex. From the recent results obtained in nonconventional attack at <I>ipso</I> position, some comment was added about the difficulty of finding structual relationship between intermediate complexes and products.
- 社団法人 有機合成化学協会の論文
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