有機反応理論の流れについて
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概要
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The organic electronic theory was constructed on the concepts of electron density and delocalization energy, and introduced some hypothetical latent factors to correlate the chemical reactivities of substrates with structures. The latent factors were used successfully to deduce reaction mechanism. However, with accumulation of facts being inexplicable with electronic theory, the theory had to give way to quantum chemistry based on perturbation method. Generally chemical studies take the processes being similar to the life of human being : birth, growth, senility and death. The causes turning the processes might be made obvious by means of case studies.
- 社団法人 有機合成化学協会の論文