ロジウム錯体を用いた接触的炭素-炭素結合生成

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概要

• 論文の詳細を見る

• Recent aspect of rhodium-catalyzed reactions is briefly surveyed from the view point of the carbon-carbon bond formation which is attained under almost neutral conditions. Topics focused here are carbene transfer, [4 + 2] cyclocoupling, aldol and Michael type coupling, and carbonylations in which a certain type of rhodium complex behaves efficiently. A unique character of rhodium is demonstrated in the field of incorporation of CO, especially silylformylation which is accomplished by a combined use of triorganosilane, CO, and a rhodium complex in the presence of acetylenic compounds, aldehydes, or epoxides. α-Silylmethylene-β-lactones and lactams are readily derived from the corresponding propargyl alcohol and propargylamine, respectively, under analogous procedure in the presence of a small amount of DBU. Bicyclo [3.3.0] octenone frameworks are also constructed by cyclocarbonylation of 1, 6-diyne derivatives.

• 社団法人 有機合成化学協会の論文

著者

• 松田 勇

  名古屋大学大学院工学研究科物質制御工学専攻

• 松田 勇

  名古屋大学大学院工学研究科

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