Catalytic Reduction of Aromatic Nitro Compounds in the Presence of Water. II:Rates of hydrogenation of nitro compounds

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概要

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• From the result of reduction of nitro compound by use of N-3 catalyst in the preceeding report it can be explained that the rate equation is first order for nitro compound and zero order for hydrogen. In the case of using N-103 catalyst, with difference from N-3 catalyst, the reduction of nitrobenzene to aniline was disturbed by the intermediates and the rate equation derived from the consideration that the intermediate was removed by aniline was able to explainthe expermental results. The reductions of various compouds which are consideredas the intermedi ate compounds, have been carried out, and from there it can beassumed that the intermediate to disturb these reduction is nitrosobenzene .

• 社団法人 有機合成化学協会の論文

著者

• 佐野 政

  三井化学KK中央研究所

関連論文

• Catalytic Reduction of Aromatic Nitro Compounds in the Presence of Water. III:Effects of amines
• Catalytic Reduction of Aromatic Nitro Compounds in the Presence of Water. II:Rates of hydrogenation of nitro compounds
• Catalytic Reduction of Aromatic Nitro Compounds in the Presence of Water, IV:Effects of phenylhydroxylamine

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