プロピレンの塩素によるパークレンと四塩化炭素の製造

概要

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Conditions for reaction of formation of carbon tetrachloride and perchloroethylene by the thermal chlorinolysis of propylene have been clarified. A reaction vessel which forms no carbon is made at first, then the effects of molar ratios of chlorine and propylene, the temperature and the time for staying in vessel have been investigated. The mechanism of formation of by-product hexachlorobenzene and the catalyst for chlorinolysis of high boiling fractions of partially chlorinated hydrocarbon has been investigated and its effect was confirmed.
社団法人有機合成化学協会の論文