Ene反応を用いる有機合成の最近の進歩

概要

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Recently much attention has been focussed on ene reactions, and their synthetic utility has been increased because of their high regio- and stereospecificity. Ene reaction is based on addition of a compound with electron-deficient multiple bond (an enophile) to an olefin possessing an allylic hydrogen (an ene).<BR>Intermolecular ene reactions are classified by functional groups in enophiles. The differences between thermal reactions and Lewis acid catalyzed ones are discussed.<BR>Intramolecular ene reactions including metallo-ene systems are reviewd according to the classification (Type I- III) reported by Oppolzer.
社団法人有機合成化学協会の論文