In situ Obervation of the Pressure Induced Amorphization of GeO2.
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概要
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In order to study the stability field of GeO2 under high pressure at room temperature, an in situ observation was made by using a diamond anvil pressure cell, an optical microscope and a high speed VTR. At about 6.5GPa, a transparent single-crystal of α-quartz type GeO2 quickly changed to a translucent material which was found to be X-ray amorphous. The loss of transparency induced by the transformation is attributed to the pulverization due to the large volume change (approximately 10%), which causes the increase of refractive index and introduces the imperfection into the single-crystal.
- 日本学士院の論文
著者
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YAMANAKA Takamitsu
College of General Education, Osaka University
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KAWASAKI Shinji
Faculty of Science, Hokkaido University
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TAKUBO Hiroshi
College of General Education, Osaka University
関連論文
- In situ Obervation of the Pressure Induced Amorphization of GeO2.
- Structural analysis of orthorhombic ZrO2 by high resolution neutron powder diffraction.