Synthesis of new disiloxane-containing polymers
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概要
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Synthesis of new disiloxane-containing polymers is described. New oxygen permeable membrane polymers and side-chain liquid crystalline polymers were synthesized by taking advantage of low rotational barrier energy around silicon-oxygen bond. Stereoregular poly[(methylphenylsilylene)trimethylene] and optically active poly[{(1S)-1-(1-naphthyl)-1-phenyl-3, 3-dimethyldisiloxan-1, 3-diyl}ethylene] were synthesized for the first time starting from optically active allylhydrosilane and optically active 1-vinyl-3-hydrodisiloxane, respectively.
- 日本学士院の論文
著者
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Kawakami Yusuke
Graduate School Of Materials Science Japan Advanced Institute Of Science And Technology
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KISHIMOTO Norihisa
Graduate School of Materials Science, Japan Advanced Institute of Science and Technology
関連論文
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- Synthesis and Optical Activity of Polyamides Derived from Optically Active Spiro[3.3]heptane - 2,6 - dicarboxylic Acid
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- Elucidation of the Stereochemical Pathway to Isotactic Poly[(methylphenylsilylene)trimethylene] from Allylmethylphenylsilane
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- Synthesis of Liquid Crystalline Oligomeric Polyoxetanes with Two Mesogenic Groups in the Repeating Unit
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