Calculation of fundamental vibration frequencies of tritium-substituted halomethanes for tritium separation by infrared lasers.

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概要

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• The fundamental vibration frequencies of twelve tritium-substituted halomethanes were calculated with a view to finding suitable molecules possessing selective absorption bands situated within the range of infrared laser tuning. The calculations were performed by the Wilson <I>FG</I> matrix method, using the force constants reported by Plyler & Benedict. These calculations were applied to 15 hydrogen- and deuterium-substituted molecules, which resulted in an average deviation of 2.3% from the observed frequencies. Several tritium-substituted halomethanes have been found promissing for use as working molecules for tritium separation by infrared laser.

• 一般社団法人 日本原子力学会の論文

著者

• ARAI Shigeyoshi

  Laser Photochemistry, The Institute of Physical and Chemical Research

• ISHIKAWA Yo-ichi

  Laser Photochemistry, The Institute of Physical and Chemical Research

• NAKANE Ryohei

  Laser Photochemistry, The Institute of Physical and Chemical Research

関連論文

• Calculation of fundamental vibration frequencies of tritium-substituted halomethanes for tritium separation by infrared lasers.

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