Uranium isotope separation by cation exchange chromatography using uranous sulfate complexes.
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A nearly ideal displacement chromatography has been realized with an eluent of MgSO<SUB>4</SUB> and H<SUB>2</SUB>SO<SUB>4</SUB> in the study of uranium isotope separation by means of cation exchange chroma-tography using uranous sulfate complexes. Uranium-235 was enriched at the end of the chromatogram and <SUP>238</SUP>U was enriched at the front. Two long distance displacement ex-periments have been carried out, keeping an isotopic plateau region on the chromatogram. Consequently, good accumulation of the isotopic fractionation based on uranous-sulfate com-plex formation reactions obtained. The separation coefficient ε of this system was estimated to be about 5×10<SUB>-5</SUB>.
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