Method of decomposing methyl and ethyl nitrates.

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概要

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• Methyl nitrate (CH<SUB>3</SUB>NO<SUB>3</SUB>) and ethyl nitrate (C<SUB>2</SUB>H<SUB>5</SUB>NO<SUB>3</SUB>) generate in the radioiodine treatment system of reprocessing, when organic iodides are reacted with silver-impregnated silica gel (an adsorbent, e. g. AC6120) or with hyperazeotropic nitric acid in Iodox process<SUP>(1)</SUP>. Since such alkyl nitrates are potentially explosive, their accumulation in the system should be avoided by an appropriate device ; however, the related literature is little. The present work offers a method of decomposing them through their reactions with nitrogen dioxide (NO<SUB>2</SUB>) on zeolites.

• 一般社団法人 日本原子力学会の論文

著者

• Sakurai Tsutomu

  Physical Chemistry Laboratory Japan Atomic Energy Research Institute

• Takahashi Akira

  Physical Chemistry Laboratory Japan Atomic Energy Research Institute

関連論文

• Trapping and Measuring Radioiodine (Iodine-129) in Cartridge Filters
• Photooxidation of Iodine Catalyzed by Uranyl Nitrate
• Krypton fixation using KrF2,(I) Thermal decomposition of krypton complex KrF22SbF5.:Thermal Decomposition of Krypton Complex KrF2•2SbF5
• Krypton Fixation using KrF2, (II):Its Interactions with Some Zeolites
• Interaction of ruthenium tetroxide with stainless steel.
• Method of decomposing methyl and ethyl nitrates.
• Catalytic Effect of Silver-Impregnated Silica-Gel (AgS) on Reaction of Methyl Iodide with Nitrogen Dioxide.
• Interaction of Iodine with an Extractant of 30% TBP/70% n-Dodecane.

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