A STUDY ON THE THERMODYNAMIC PROPERTIES OF ASSOCIATED SOLUTIONS BY LINEAR ASSOCIATION MODELS
スポンサーリンク
概要
- 論文の詳細を見る
The excess thermodynamic properties of associated solutions are discussed by using the linear association models (I) and (II). The linear association model (I) deals with the self-associated system by making distinctions between the association constant and association energy of dimer formation and those of polymer formations. The results of the calculation show that the distinguishing effects are relatively small in quality. The linear association model (II) is proposed as one of the models for the system having the species associated with like and unlike molecules. A characteristic of this model is the existence of a maximum point on the activity coefficient curve. Good results are obtained in the application of model (II) to correlate and interpret the vapor-liquid equilibria for binary mixtures of alcohols and interacting solvents.
- 公益社団法人 化学工学会の論文
著者
-
Nitta Tomoshige
Department Of Chemical Engineering Osaka University
-
Nitta Tomoshige
Department of Chemical Engineering, Osaka University
-
KATAYAM TAKASHI
Department of Chemical Engineering, Osaka University
関連論文
- NON-EQUILIBRIUM MOLECULAR DYNAMICS FOR SIMULATING PERMEATION OF GAS MIXTURES THROUGH NANOPOROUS CARBON MEMBRANES
- MONTE CARLO SIMULATION OF ADSORPTION OF GASES IN CARBONACEOUS SLITLIKE PORES
- MONTE CARLO SIMULATIONS OF pVT RELATIONS AND ADSORPTION EQUILIBRIA OF ETHANE UNDER SUB- AND SUPERCRITICAL CONDITIONS
- A HYBRID ISOTHERM EQUATION FOR MOBILE MOLECULES ADSORBED ON HETEROGENEOUS SURFACE OF RANDOM TOPOGRAPHY
- Monte Carlo Simulation Study of Entrainer Effect on Distribution Equilibrium between Supercritical Fluids and Slitpores
- AN ADSORPTION ISOTHERM OF MULTI-SITE OCCUPANCY MODEL FOR HOMOGENEOUS SURFACE
- COMPUTER SIMULATIONS FOR ADSORPTION OF BENZENE DILUTED IN SUPERCRITICAL CARBON DIOXIDE
- IR SPECTRA OF ADSORPTION ON SILICA GEL FOR ACETONITRILE, TETRAHYDROFURAN, DIETHYL ETHER AND METHANOL-d DILUTED IN SUPERCRITICAL CARBON DIOXIDE
- GAS-PHASE ADSORPTION CHARACTERISTICS OF HIGH-SURFACE AREA CARBONS ACTIVATED FROM MESO-CARBON MICRO-BEADS
- A STUDY ON THE THERMODYNAMIC PROPERTIES OF ASSOCIATED SOLUTIONS BY LINEAR ASSOCIATION MODELS
- Liquid-liquid equilibria for ternary systems of methanol-polar solvents-cyclohexane.
- A practical isotherm equation for adsorption on a heterogeneous surface and its applications to single and mixed gas adsorption on an activated carbon fiber.
- Effects of surface heterogeneity on gas permeation through slit-like carbon membranes by non-equilibrium molecular dynamics simulations.
- Vapor-liquid equilibraia for binary systems of sulfur dioxide and some organic solvents.
- TERNARY LIQUID-LIQUID EQUILIBRIUM DATA FOR METHANOL-CYCLOPENTANE-CYCLOHEXANE SYSTEM AND DISCUSSION BY THE KRETSCHMER-WIEBE EQUATION
- SOLUBILITIES OF NITROGEN IN MIXED SOLVENTS: CYCLOHEXANE-iso-OCTANE AND n-PROPANOL-iso-OCTANE MIXTURES
- Resolution of enantiomers by supercritical fluid chromatography with cellulose tris(phenylcarbamate) coated on silica gel.
- A NEW INTERPRETATION OF THE WILSON EQUATION, AS A SHORT-CUT FORM OF THE ASSOCIATED SOLUTION THEORY
- Gas-phase adsorption equilibria for acetone, diethyl ether, methanol, and water on activated carbon fiber.
- Nitrogen solubility and vapor pressure of binary mixed solvents containing benzene, carbon tetrachloride, cyclohexane and 1-hexane.
- Computer Simulation Studies on Gas Permeation through Nanoporous Carbon Membranes by Non-Equilibrium Molecular Dynamics.
- Comparison of Adsorption Isotherms of Acetone in Super Critical Carbon Dioxide by Chromatography and IR Spectroscopy.