高分子液晶
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概要
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Recently, the mesomorphic structure has been found in the molten and dissolved states and even the solid state of many kinds of polymers. The history of polymer liquid crystals is surveyed briefly in this paper. Polymers which exhibit a liquid crystalline phase are classified into semiflexible or rigid polymers, according to the flexibility of their main chain, or into polymers with mesogenic side groups, polymers with rigid segments, or polymers with a rigid block, depending on their molecular structure. The liquid crystalline structure of these polymers is interpreted on the basis of the molecular structure. Recent theoretical works on the formation of lyotropic polymer liquid crystals and on the structure and properties of polymer liquid crystals are also briefly reviewed. The application of polymer liquid crystals is discussed, taking account of the characteristics of polymer liquid crystals.
- 日本生物物理学会の論文