高強度低合金鋼の水素中引張変形に伴う水素侵入挙動

概要

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Absorption of hydrogen in a high-strength nickel–chromium–molybdenum steel during tensile deformation in 0.5 MPa gaseous hydrogen was examined using a thermal desorption analysis method. The tensile strength of the specimen was varied in the range from 1214 to 947 MPa by heat treatment. The dislocation density of the specimens was measured by X-ray diffractometry after tensile testing in a hydrogen atmosphere. The hydrogen content absorbed during tensile deformation increased with increasing tensile strain in proportional elastic range until just before yielding. The yield stress was defined as 0.2% proof stress in this work. At the same tensile strains, the hydrogen content of lower-strength specimens was larger than that of higher-strength specimens. The dislocation density gradually decreased until just before yielding, corresponding to the proportional increase of hydrogen content to the tensile strain. This implies that the hydrogen absorption behavior during tensile deformation in gaseous hydrogen is related to the motion of mobile dislocations initially contained in the specimens. The activation energy for desorption of hydrogen absorbed during tensile deformation did not depend on the strength of the steel. This indicates that the trap sites of hydrogen atoms created through the tensile deformation were the same regardless of the strength levels.