Development of P-Spiro Chiral Aminophosphonium Salts as a New Class of Versatile Organic Molecular Catalyst

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概要

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• A series of P-spiro chiral tetraaminophosphonium salts have been designed and synthesized as a new class of organic molecular catalysts, and their inherent abilities to exert four different, synthetically relevant asymmetric catalyses have been brought out through the unique molecular design on a single core structure, N4P+. Further, these catalyses have been applied to the development of various C-C, C-P, and C-N bond-forming reactions, in which the remarkably high catalytic performances and stereocontrolling abilities of the chiral tetraaminophosphonium salts have been successfully demonstrated.

• 社団法人 有機合成化学協会の論文

著者

• Uraguchi Daisuke

  Department Of Applied Chemistry Graduate School Of Engineering Nagoya University

• OOI Takashi

  Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

関連論文

• Diastereo- and Enantioselective Direct Henry Reaction of Pyruvates Mediated by Chiral P-Spiro Tetraaminophosphonium Salts
• Evaluation of the Relationship between the Catalyst Structure and Regio- as well as Stereoselectivity in the Chiral Ammonium Bifluoride-Catalyzed Asymmetric Addition of Silyl Nitronates to α, β-Unsaturated Aldehydes
• Development of P-Spiro Chiral Aminophosphonium Salts as a New Class of Versatile Organic Molecular Catalyst
• Organoaluminum-Promoted Cyclization of Olefinic Epoxides. A New and Stereoselective Approach to Cyclohexane Frameworks
• Development of P-Spiro Chiral Aminophosphonium Salts as a New Class of Versatile Organic Molecular Catalyst

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