異種酸化物を被覆した酸化鉄の還元酸化サイクル反応による水素製造

概要

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The hydrogen energy society is desirable to mitigate global warming. The redox cycle reaction of iron oxide Fe3O4 which can generate 4.8 mass% hydrogen is considered as one of means to storage and supply it. However, this reaction is known to be significantly retarded due to sintering iron oxide or iron particles. In this work, influence of foreign oxides coating on the surface of iron oxide fines is examined to improve the reaction efficiency.Al2O3 coating enhanced the reaction efficiency until 97% even for more redox reaction cycles which is superior to SiO2 coating, probably because of difference of gas diffusivity through coating layers.Redox reaction rates in this work were nearly one order of magnitude larger than previous ones, which were obtained with samples prepared by coprecipitation from solution containing additives.The activation energy for reduction of Al2O3 coating samples was obtained 41.2 kJ/mol close to that in a literature.