Reversible Change of Interlayer Spacing of Layered Double Hydroxides Containing Organic Carboxylates
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概要
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Layered double hydroxide (LDH) has positive charge between the layers and is known as anion exchangeable clay being able to intercalate various organic and inorganica nions. In this study, organic-inorganic layered nanohybrids were prepared by intercalation of organic carboxylate anions into Zn/Al LDH in an aqueous solution. Four intercalation compounds were prepared by the reactions of succinate, terephthalate, 4-pyridinecarboxylate, and p-hydroxybenzoate anions with Zn/Al LDH in aqueous solution. Interlayer spacing of these four intercalation compounds decreased by the thermal treatment at 363 K, and recovered by the treatment in water, reversibly.
- 公益社団法人 日本セラミックス協会の論文
著者
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Kadokawa Jun-ichi
Graduate School Of Science And Engineering Kagoshima University
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HATANO Bunpei
Graduate School of Human and Environmental Studies, Kyoto University
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SUDO Haruo
Graduate School of Science and Engineering, Yamagata University
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TAGAYA Hideyuki
Graduate School of Science and Engineering, Yamagata University
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HATANO Bunpei
Graduate School of Science and Engineering, Yamagata University
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KADOKAWA Jun-ichi
Graduate School of Science and Engineering, Yamagata University
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