Synthesis of Quinolactacide via an Acyl Migration Reaction and Dehydrogenation with Manganese Dioxide, and Its Insecticidal Activities
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概要
- 論文の詳細を見る
Quinolactacide isolated from Penicillium citrinum F 1539 was synthesized and evaluated for its insecticidal activities. The key steps of the total synthesis were an acyl migration reaction of the enol ester intermediate and dehydrogenation of tetrahydroquinolactacide with manganese dioxide. The synthesized quinolactacide showed 100% and 42% mortality against the green peach aphid (Myzus persicae) and diamondback moth (Plutella xylostella) at 500 ppm, respectively.
- 社団法人 日本農芸化学会の論文
- 2006-01-23
著者
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Imai Tetsuya
Naruto Research Center Otsuka Chemical Co. Ltd.
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Abe Masaki
Naruto Research Center Otsuka Chemical Co. Ltd.
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ISHII Naoki
Naruto Research Center, Otsuka Chemical Co., Ltd.
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USUI Makio
Naruto Research Center, Otsuka Chemical Co., Ltd.
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Usui Makio
Naruto Research Center Otsuka Chemical Co. Ltd.
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Ishii Naoki
Naruto Research Center Otsuka Chemical Co. Ltd.
関連論文
- Isolation of an insecticidal compound oxalicine B from Penicillium sp. TAMA 71 and confirmation of its chemical structure by X-ray crystallographic analysis
- Synthesis of Quinolactacide via an Acyl Migration Reaction and Dehydrogenation with Manganese Dioxide, and Its Insecticidal Activities
- Quinolactacide, a New Quinolone Insecticide from Penicillium citrinum Thom F 1539
- Studies on the Insecticidal Properties of Benfuracarb against the Brown Rice Planthopper, Nilaparvata lugens (STÅL) (Hemiptera: Delphacidae)