A Novel Lepidopteran Sex Pheromone Produced by Females of a Lithosiinae Species, Lyclene dharma dharma, in the Family of Arctiidae
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概要
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Female moths of Lyclene dharma dharma (Arctiidae, Lithosiinae) produced three pheromone components (I–III), which strongly stimulated male antennae. Using GC–MS analysis and chemical derivatizations, the following structures were estimated: 6-methyl-2-octadecanone (I), 14-methyl-2-octadecanone (II), and 6,14-dimethyl-2-octadecanone (III). While the stereochemistry of the chiral centers could not be determined because it was difficult to collect a sufficient amount of the natural pheromone, the plain structures of I and II were confirmed by synthesis of the racemic mixtures starting from diols. These methyl-branched ketones have not been identified as a natural product, indicating that they constitute a new chemical group of lepidopteran female sex pheromones.
- 社団法人 日本農芸化学会の論文
著者
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Do Nguyen
Graduate School of Bio-Applications and Systems Engineering (BASE), Tokyo University of Agriculture
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ANDO Tetsu
Graduate School of Bio-Applications and Systems Engineering (BASE), Tokyo University of Agriculture
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Kinjo Masakatsu
Iriomote Station, Tropical Biosphere Research Center, University of the Ryukyus
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ADACHI Yasushi
Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Tec
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Yamamoto Masanobu
Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Tec
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Kamata Tomoya
Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Tec
関連論文
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