Non-metal-requiring Catalyst Contained in Recovered Methyl Linolenate from an Autoxidizing Sample

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概要

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• Non-metal-requiring catalysts in recovered methyl linolenate from an autoxidizing sample were unstable on contact with silicic acid and the activity varied widely with the way of recovery, countercurrent extraction and column chromatography under different conditions. After reduction with stannous chloride, a substance was found which was characteristically present in the products derived from the recovered methyl linolenate high in the catalytic activity. It was tentatively identified by MS, IR, OsO4 oxidation-IO4- oxidation, and LiAlH4 reduction-IO4- oxidation as methyl 9, 13-dihydroxy-10-epoxy-15-octadecenoate.

• 社団法人 日本農芸化学会の論文

著者

• Morita Makio

  Department of Agricultural Chemistry, Faculty of Agriculture, The University of Tokyo

関連論文

• New Geometric Isomers of Oxooctadecadienoate in Copper-catalyzed Decomposition Products of Linoleate Hydroperoxide
• Methyl Linoleate Dimer and Methyl 8-Phenyloctanoate in the Coppercatalyzed Decomposition Products of Methyl Linoleate Hydroperoxides
• Non-metal-requiring Catalyst Contained in Recovered Methyl Linolenate from an Autoxidizing Sample

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