Synthesis of amino acids and related compounds. Part XXVII. A useful and biomimetic synthesis of N-acyl .ALPHA.,.BETA.-dehydroalanine from aspartic acid.

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概要

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• N-Acyl α, β-dehydroalanines (1) were synthesized from the corresponding N-acyl aspartic acids by a one-pot procedure through a biomimetic oxidative β-decarboxylation. In particular, the transformation using methanol-sodium hypochlorite aqueous solution, which served for N-chlorination and dehydrochlorination, afforded good yields of (1).

• 公益社団法人 日本農芸化学会の論文

著者

• SEKI Masahiko

  Department of Synthetic Chemistry, Research Laboratory of Applied Biochemistry, Tanabe Seiyaku Co., Ltd.

関連論文

• Synthesis of amino acids and related compounds. Part XXVII. A useful and biomimetic synthesis of N-acyl .ALPHA.,.BETA.-dehydroalanine from aspartic acid.

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