Preparation of (-)-cis- and (-)-trans-2, 4-Dimethylcyclohexan-1-ones for the Synthesis of Cycloheximides

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概要

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• Microbial reduction of (±)-2, 4-dimethylcyclohex-2-en-1-one by Beauveria sulfurescens led mainly to two isomers of 2, 4-dimethylcyclohexanols. By oxidation of these alcohols, chiral building blocks for cycloheximide synthesis were obtained, namely (-)-(2R, 4R)-2, 4-dimethylcyclohexan-1-one and (-)-(2R, 4S)-2, 4-dimethylcyclohexan-1-one.

著者

• VESCHAMBRE Henri

  Laboratoire de Chimie Organique Biologique, Universite de Clermont-II

関連論文

• Preparation of (-)-cis- and (-)-trans-2, 4-Dimethylcyclohexan-1-ones for the Synthesis of Cycloheximides

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