Prevention of activated carbon bed ignition and degradation during the recovery of cyclohexanone.

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概要

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• Oxidation of cyclohexanone adsorbed on activated carbon was investigated in relation to solvent recovery. It became clear that the respective reactions through which 1,2-cyclohexanedione and adipic acid formed were largely responsible for carbon bed ignition and carbon degradation. Results were explained assuming that the former reaction is of pseduo-first-order and proceeds much faster than the latter. Further, it was concluded that the concentration of carbonyl group on the carbon surface and that of oxygen in the gas phase affected both reactions strongly.

• The Society of Chemical Engineers, Japanの論文

著者

• IKEDA Hiroshi

  Dept. Biosphere-Geosphere System Sci., Okayama Univ. Sci.

• Takeuchi Yasushi

  Dept. of Ind. Chem., Meiji Univ.

• Mizutani Masataka

  Dept. of Ind. Chem., Meiji Univ.

関連論文

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• Prevention of activated carbon bed ignition and degradation during the recovery of cyclohexanone.

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