Hydrogenolysis of methyl oleate over oxide catalyst derived from hydrogen storage alloy.
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概要
- 論文の詳細を見る
A mixed oxide catalyst was prepared from a binary hydrogen storage alloy, Mg<SUB>2</SUB>Cu, and its activity and selectivity were compared with those of conventional CuCrO catalyst. The catalyst's activity was stable for the synthesis of C<SUB>18</SUB> alcohol by gas-phase hydrogenolysis of methyl oleate in a continuous-flow reactor at 553 K under atmospheric pressure. Considerable amounts of unsaturated alcohol were produced together with saturated alcohol. From a kinetic study the rate equation was formulated for each alcohol. From XRD analysis, active sites are thought to be copper species on MgO support.
- The Society of Chemical Engineers, Japanの論文
著者
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Tagawa Tomohiko
Department Of Chemical Engineering Nagoya University
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Goto Shigeo
Department Of Chemical Engineering Nagoya University
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Chikamatsu Nobuyasu
Department Of Chemical Engineering Nagoya University
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