NEW INVARIANT ASYMMETRIC MIXING RULES
スポンサーリンク
概要
- 論文の詳細を見る
New invariant asymmmetric mixing rules were developed which obeyed the boundary condition of the second virial coefficient. These mixing rules were incorporated into the PRSV (Peng-Robinson-Stryjek-Vera) equation of state and applied to vapor-liquid equilibrium (VLE) calculations with emphasis on aqueous mixtures. The new mixing rules could improve VLE calculations for binary aqueous systems while an asymmetric interaction constant (l12) and temperature-dependent q12 were used. The new model reasonably predicts the VLE behavior for several aqueous weak electrolyte systems and is generally better than the API-Sour model at elevated temperature applications.
- 社団法人 化学工学会の論文
- 1996-02-20
著者
-
Lee Ming-jer
Department Of Chemical Engineering National Taiwan Institute Of Technology
-
Liu In-tung
Department Of Chemical Engineering National Taiwan Institute Of Technology
関連論文
- An Improved Model of Second Virial Coefficients for Polar Fluids and Fluid Mixtures
- CORRESPONDING-STATES MODEL FOR VISCOSITY OF LIQUIDS AND LIQUID MIXTURES
- Kinetics of Catalytic Esterification of Acetic Acid with Amyl Alcohol over Amberlyst 15
- PVT of Fractionation Cuts of Poly (ethylene glycol) and Poly (propylene glycol) from 298 K to 338 K and Pressures up to 30 MPa
- CORRESPONDING-STATES MODEL FOR THERMAL CONDUCTIVITY OF LIQUIDS AND LIQUID MIXTURES
- DENSITY AND VISCOSITY CALCULATIONS FOR POLAR SOLUTIONS VIA NEURAL NETWORKS
- NEW INVARIANT ASYMMETRIC MIXING RULES
- CORRELATION OF k-_ FOR SVE SYSTEMS CONTAINING A SUPERCRITICAL FLUID