Reaction Characteristics of CaSO4/CaSO4 1/2H2O Reversible Reaction for Chemical Heat Pump
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概要
- 論文の詳細を見る
We had proposed chemical heat pumps using a reversible calcium sulphate/water reaction system for effective waste energy utilization. However, more reaction kinetics studies are necessary for this reaction system, especially for different atmosphere condition and different materials. As a result, the reaction equilibrium line of CaSO<SUB>4</SUB> in the closed system like CHP system was found to be close to that in the open system. It means that the CHP using CaSO<SUB>4</SUB>/CaSO<SUB>4</SUB>·1/2H<SUB>2</SUB>O reversible reaction stores under 373 K level thermal energy, and releases the same level hot heat and 273 K level cold heat. Furthermore, the effects of material size on the reaction rates could be calculated by the proposed equations, which enable the effective CHP reactor design.
- The Society of Chemical Engineers, Japanの論文
著者
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Ogura Hironao
Division of Architecture and Urban Science, Graduate School of Engineering, Chiba University
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Haguro Masahiro
Division of Architecture and Urban Science, Graduate School of Engineering, Chiba University
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Shibata Yasuhiro
Division of Architecture and Urban Science, Graduate School of Engineering, Chiba University
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Otsubo Yasufumi
Division of Architecture and Urban Science, Graduate School of Engineering, Chiba University