Thermodynamic Relationship between the Enthalpy Interaction Parameter and Entropy Interaction Parameter in Liquid Iron-Nitrogen Based Ternary Alloys
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概要
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A statistical thermodynamic solution model based on the free volume theory is applied to liquid iron-nitrogen based ternary alloys to derive the relationship between the enthalpy interaction parameter and the entropy interaction parameter. A linear relationship between those parameters is obtained. Then, Wagner's interaction parameters of nitrogen with some metallic elements in liquid iron alloys are evaluated. These results show that the free volume of the solute elements is an important factor to determine the excess entropy terms in those alloys.
- Carl Hanser Verlagの論文
Carl Hanser Verlag | 論文
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