Electrooxidative Cyclization of Benzylidenaminothiophenols to the Corresponding 2-Arylbenzothiazoles Electrooxidative Cyclization of Benzylidenaminothiophenols to the Corresponding 2-Arylbenzothiazoles

スポンサーリンク

概要

• 論文の詳細を見る

• Copyright © 2009 The Japan Institute of Heterocyclic Chemistryhttp://www.heterocycles.jp/library/abstract.php?article=2797Several benzylideneaminothiophenols were electrochemically oxidized in methanol containing sodium acetate as the supporting electrolyte, to afford the corresponding 2-arylbenzothiazols. The reaction proceeded via intramolecular cyclization involving the formation of a new bond between the benzylic carbon of the substrate and the sulfur of the thiol group. Based on the yields, room temperature and the use of two equivalents of sodium acetate relative to the substrate as the supporting electrolyte were　found to be the optimal reaction conditions. The electrooxidation presumably involves a two-electron oxidation process.

• The Japan Institute of Heterocyclic Chemistryの論文
• 2008-01-01

著者

• Yoshida Takashi

  Matsuyama Univ. Matsuyama Jpn

関連論文

• スギヒラタケに含まれる特徴的な長鎖脂肪酸について
• Novel application of electrooxidative method for the cyclization of N-benzyl-2-(hydroxymethyl)- and N-benzyl-2-(2-hydroxyethyl)piperidines
• P-236 CONJUGATED LONG-CHAIN FATTY ACIDS OF PLEUROCYBELLA PORRIGENS
• Urinary Excretion of Anthocyanins in Humans after Cranberry Juice Ingestion
• Water-Soluble Complexes Formed by Natural Polyphenols and Bovine Serum Albumin : Evidence from Gel Electrophoresis
• Novel application of an electrooxidative method for the formation of a tetrahydrofuran ring from 5-hydroxy-2-pentanone phenylhydrazone
• Electrooxidative Cyclization of Hydroquinolyl Alcohols
• Electrooxidative Cyclization of Benzylidenaminothiophenols to the Corresponding 2-Arylbenzothiazoles Electrooxidative Cyclization of Benzylidenaminothiophenols to the Corresponding 2-Arylbenzothiazoles

スポンサーリンク