Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes

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概要

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• Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80℃ to produce the corresponding arylboronates in high yields with excellent regioselectivities.

• 2010-01-07

著者

• KIKUCHI Takao

  Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University

• ISHIYAMA Tatsuo

  Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University

• Ishiyama T

  Hiroshima Univ. Higashi‐hiroshima

• Ishiyama Tatsuo

  Division Of Molecular Chemistry Graduate School Of Engineering Hokkaido University

• Ishiyama Takeshi

  Department Of Chemistry Graduate School Of Science Hiroshima University

• Itoh Hiroshi

  Division Of Chemical Process Engineering Graduate School Of Engineering Hokkaido University

• Kikuchi Takao

  Division Of Chemical Process Engineering Graduate School Of Engineering Hokkaido University

• Ishiyama Tatsuo

  Division Of Chemical Process Engineering Graduate School Of Engineering Hokkaido University

関連論文

• Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes
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