DME Dissociation Reaction on Platinum Electrode Surface : A Quantitative Kinetic Analysis by In Situ IR Spectroscopy
スポンサーリンク
概要
- 論文の詳細を見る
The kinetics of electrocatalytic dissociation reaction of dimethyl ether (DME) on a platinum (Pt) polycrystalline electrode in an acidic solution yielding carbon monoxide (CO) has been quantitatively analyzed by in situ IR spectroscopy in the potential region between 100 and 500 mV (vs reversible hydrogen electrode). A two-step consecutive reaction model, an initial dehydrogenation step followed by a CO formation step, is proposed for the dissociation process of the DME molecule. The mechanism of the DME dissociation on the Pt electrode surface is discussed based on the kinetic analysis.
- Electrochemical Societyの論文
Electrochemical Society | 論文
- DME Dissociation Reaction on Platinum Electrode Surface : A Quantitative Kinetic Analysis by In Situ IR Spectroscopy
- Electrochemical Functionalization of InP Porous Nanostructures with a GOD Membrane for Amperometric Glucose Sensors
- Thickness dependence of proton conductivity of amorphous aluminosilicate nanofilm
- Effect of SnO2 Deposition Sequence in SnO2-Modified PtRu/C Catalyst Preparation on Catalytic Activity for Methanol Electro-Oxidation
- An In Situ Electrochemical Quartz Crystal Microbalance Study of the Dissolution Process of a Gold Electrode in Perchloric Acid Solution Containing Chloride Ion