Stereoselective synthesis of (Z)-β-fluoro-α,β-unsaturated esters from (Z)-2-fluoro-1-alkenyliodonium salts

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概要

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• (Z)-β-Fluoro-α,β-unsaturated esters were stereoselectively synthesized from (Z)-2-fluoro-1-alkenyliodonium salts by the Pd-catalyzed methoxycarbonylation reaction. The reaction proceeded at room temperature and various functional groups on the substrate can tolerate the reaction conditions.

• Elsevier B.V.の論文

著者

• Hara Shoji

  Div. Of Chemical Process Engineering Graduate School Of Engineering Hokkaido Univ. 8 Kita 13-jo Nish

• Yoshida Masanori

  Div. Of Chemical Process Engineering Graduate School Of Engineering Hokkaido Univ. 8 Kita 13-jo Nish

関連論文

• Stereoselective synthesis of fluoroalkenes via (Z)-2-fluoroalkenyliodonium salts
• Stereoselective synthesis of (Z)-β-fluoro-α,β-unsaturated esters from (Z)-2-fluoro-1-alkenyliodonium salts
• Fluorination of Ketones Using Iodotoluene Difluoride
• α-Fluorination of β-dicarbonyl compounds using p-iodotoluene difluoride under neutral conditions

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