Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compounds

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概要

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• The hydrogenation of ethanediol 1-phenylethenylboronic ester was carried out at −20 °C under a hydrogen atmosphere (9 atm) in the presence of [Rh(cod)2]BF4–(R)-BINAP (3 mol%). After alkaline hydrogen peroxide oxidation, the reaction gave 1-phenylethanol with 80% e.e.

• Elsevier Science B.V.の論文
• 2002-01-18

著者

• Ueda M

  Hokkaido Univ. Sapporo Jpn

関連論文

• A Palladium-Catalyzed Biaryl Coupling of Arylboronic Acids in Aqueous Media Using A Gluconamide-Substituted Triphenylphosphine (GLCAphos) Ligand
• Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compounds

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