An efficient synthesis of fluorocyclopentenes using fluoroalkylidenecarbenes
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概要
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An efficient synthesis of fluorocyclopentenes is described. By treatment of (2-fluoroalkenyl)iodonium salts with potassium tertbutoxide, (α-fluoroalkylidene)carbenes were generated efficiently to give fluorocyclopentenes via 1,5-C–H insertion. Fluorocyclopentenes having a functionality, such as chlorine, acetoxy or ketone, and a spiro fluorocyclopentene were synthesized in good yields.
- Elsevierの論文
- 2008-01-01
Elsevier | 論文
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