Asymmetric reductive cyclization using the intramolecular conjugate addition of enolates onto α,β-unsaturated sulfoxides
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Li(sec-Bu)3BH-mediated reductive cyclization of optically pure 8-((S)-p-tolylsulfinyl)-(2E,7Z)-octadienoate 9 and 7-(p-tolylsulfinyl)-2,6-heptadienoate 16 afforded trans-2-((p-tolylsulfinyl)-methyl)cyclohexane-1-carboxylate and trans-2-((p-tolylsulfinyl)methyl)cyclopentane-1-carboxylate, respectively, as a single isomer.
- Elsevier B.V.の論文
- 1998-01-01
Elsevier B.V. | 論文
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